全文获取类型
收费全文 | 10787篇 |
免费 | 358篇 |
国内免费 | 86篇 |
专业分类
化学 | 7687篇 |
晶体学 | 50篇 |
力学 | 266篇 |
综合类 | 1篇 |
数学 | 1544篇 |
物理学 | 1683篇 |
出版年
2023年 | 38篇 |
2021年 | 120篇 |
2020年 | 158篇 |
2019年 | 157篇 |
2018年 | 109篇 |
2017年 | 93篇 |
2016年 | 243篇 |
2015年 | 210篇 |
2014年 | 248篇 |
2013年 | 595篇 |
2012年 | 615篇 |
2011年 | 778篇 |
2010年 | 346篇 |
2009年 | 286篇 |
2008年 | 602篇 |
2007年 | 687篇 |
2006年 | 711篇 |
2005年 | 579篇 |
2004年 | 534篇 |
2003年 | 450篇 |
2002年 | 409篇 |
2001年 | 167篇 |
2000年 | 127篇 |
1999年 | 126篇 |
1998年 | 99篇 |
1997年 | 121篇 |
1996年 | 125篇 |
1995年 | 119篇 |
1994年 | 109篇 |
1993年 | 123篇 |
1992年 | 114篇 |
1991年 | 77篇 |
1990年 | 101篇 |
1989年 | 60篇 |
1988年 | 77篇 |
1987年 | 78篇 |
1986年 | 84篇 |
1985年 | 139篇 |
1984年 | 117篇 |
1983年 | 86篇 |
1982年 | 121篇 |
1981年 | 116篇 |
1980年 | 110篇 |
1979年 | 94篇 |
1978年 | 109篇 |
1977年 | 87篇 |
1976年 | 78篇 |
1975年 | 73篇 |
1974年 | 61篇 |
1973年 | 82篇 |
排序方式: 共有10000条查询结果,搜索用时 406 毫秒
71.
Bonner BE Buchanan JA Clement JM Corcoran MD Krishna NM Kruk JW Miettinen HE Moss RM Mutchler GS Nessi-Tedaldi F Nessi M Phillips GC Roberts JB Stevenson PM Tonse SR Birman A Chung SU Etkin A Fernow RC Kirk H Protopopescu SD Willutzki H Hallman T Madansky L Bar-Yam Z Dowd J Kern W King E Mayes BW Pinsky LS 《Physical review D: Particles and fields》1990,41(1):13-16
72.
Stephen D. Cohen 《Monatshefte für Mathematik》1989,107(4):291-301
Chambers andSmeets [3] have designed a windmill arrangement of linear feedback shift registers (LFSRs) to generate pn-sequences overGF(2) with high speed. When the windmill hasv vanes, the associated minimal feedback polynomial (having degreen, relatively prime tov) can be taken to have the shapef
1(x
v
)+x
n
f
2(x
–v
), where the polynomialsf
1 andf
2 have degree [n/v]. Their numerical evidence, whenv is divisible by 4, suggests that, surprisingly, there areno such windmill polynomials which are irreducible ifn±3 (mod 8), while about twice as many irreducible and primitive windmill polynomials as they expected occur ifn±1 (mod 8). A discussion of this behaviour is presented here with proofs. The brief explanation is that the Galois group of the underlying generic windmill polynomial overGF (4) is equal to the alternating groupA
n
. 相似文献
73.
Stephen D. Smith 《Geometriae Dedicata》1988,25(1-3):355-373
A discussion of results and conjectures, focussed around the extension of the modular representation theory for finite Lie-type groups to more general groups that act on building-like geometries.Based on a lecture given at the conference Groups and Geometries-Finite and Algebraic, on 26 March 1986 at Noordwijkerhout, Netherlands (a NATO Advanced Research Workshop).Partially supported by NSF Grant MCS 83-00855. 相似文献
74.
Compound 1, 2-(4-phenoxyphenylsulfonylmethyl)thiirane, is a potent and selective inhibitor for human gelatinases (J. Am. Chem. Soc. 2000, 122, 6799-6800), enzymes implicated in a number of diseases, including cancer. This compound is showing excellent promise in animal trials in a number of disease models. Large quantities of this compound were necessary for these studies. A convenient four-step synthetic route for compound 1 is described herein. The synthesis is amenable to scale-up to tens of grams and gives an overall yield of 57% for this important compound. 相似文献
75.
Copolymerization of vinyl acetate with allyl carbonates that contain isopropyl groups yields highly branched poly(vinyl acetates). 相似文献
76.
Strong, low-energy two-photon absorption in extended amine-terminated cyano-substituted phenylenevinylene oligomers 总被引:8,自引:0,他引:8
Chung SJ Rumi M Alain V Barlow S Perry JW Marder SR 《Journal of the American Chemical Society》2005,127(31):10844-10845
Three quadrupolar oligophenylenevinylenes with five rings in the conjugated backbone, terminal donor groups, and various acceptors and/or donors along the backbone were synthesized and their two-photon spectroscopic properties investigated. These chromophores exhibit large two-photon absorption cross sections over a wide wavelength range and two distinct peaks, the strongest of which (deltamax > 3600 GM) is observed at 960-970 nm, a wavelength close to twice the value of the linear absorption maximum (2lambda(1)max). The findings on these chromophores are compared with those for analogous molecules with shorter conjugation length, for which the main two-photon band is at significantly shorter wavelength than 2lambda(1)max. 相似文献
77.
Stephen G. Davies Ian A. Hunter Rebecca L. Nicholson Paul.M. Roberts Edward D. Savory Andrew D. Smith 《Tetrahedron》2004,60(35):7553-7577
α-Dibenzylamino- and α-benzyloxy- derivatives of N-acetyl-(S)-4-benzyl-5,5-dimethyloxazolidin-2-one readily undergo highly stereoselective boron mediated syn-aldol reactions with a range of aromatic and aliphatic aldehydes, generating the syn-aldol products in good to excellent yields as single diastereoisomers after purification. In the α-dibenzylamino series, deprotection of the functionalised aldol fragments to the corresponding α-amino-β-hydroxy methyl ester or α-amino-β-hydroxyaldehyde proved problematic, with a range of N- and O-protecting groups giving mixtures of products arising from endocyclic and exocyclic cleavage pathways. However, in the α-benzyloxy series, O-silyl protection of the aldol products, and subsequent DIBAL reduction gives stereoselectively the corresponding N-1′-hydroxyalkyloxazolidin-2-ones, which undergo base promoted fragmentation to the desired highly functionalised and differentially protected α,β-dihydroxyaldehydes in good yields and without loss of stereochemical integrity. 相似文献
78.
Scott Charles D. Woodward Charlene A. Thompson James E. Blankinship Stephen L. 《Applied biochemistry and biotechnology》1990,24(1):799-815
Applied Biochemistry and Biotechnology - Both oxidative and reductive enzymes can be utilized to enhance coal solubilization in aqueous and organic media. Aerobic solubilization was carried out... 相似文献
79.
Merkx M Kopp DA Sazinsky MH Blazyk JL Müller J Lippard SJ 《Angewandte Chemie (International ed. in English)》2001,40(15):2725
The cover picture shows in the background the whole cell of a methanotrophic bacterium on which are superimposed components of methane monooxygenase (the structure of the hydroxylase component (top), one of the two four-helix bundles that house the catalytic diiron centers (left)) and a schematic diagram of the catalytic cycle by which the enzyme converts dioxygen and methane into methanol and water. More about this unusual enzyme system is reported by Lippard et al. on p. 2782 ff. 相似文献
80.